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中央高校基本科研业务费专项资金(TD2011-14)

作品数:7 被引量:8H指数:2
相关作者:曹金珍马尔妮王佳敏孙敏洋钟卉更多>>
相关机构:北京林业大学教育部更多>>
发文基金:中央高校基本科研业务费专项资金北京市大学生科学研究与创业行动计划更多>>
相关领域:农业科学轻工技术与工程更多>>

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Properties of Compound Systems of Paraffin Wax Emulsion and Copper Azole and Treated Wood被引量:1
2014年
[Objective]Preservation and waterproof treatment are two crucial parts in wood protection, which can not only extend the service time, but also expand the application range of wood products. [Method] This work combined CA with paraffin wax emulsion to treat wood samples, and basic properties of the compound system, such as stability (storage stability and centrifugal stability), particle size and pH val-ue, and water repel ency (water absorption, shrinkage and swel ing) of treated sam-ples were investigated. [Result and Conclusion] 1) the compound systems of CA and paraffin latex had a favorable miscibility and stability; 2) compared with untreated wood, CA-treated samples showed poor water repel ing properties, whereas samples treated with the compound systems indicated an obvious reduction in water absorp-tion, and the shrinkage and swel ing of them were improved as wel .
王佳敏汤少怀马尔妮曹金珍王露茜
关键词:WOODCA
铜唑(CA-C)/石蜡防水剂复配处理材的金属腐蚀性能被引量:3
2015年
【目的】在 CA防腐剂中添加石蜡乳液防水剂,探究石蜡乳液对处理材金属腐蚀性的影响,为解决木材防腐行业中的金属腐蚀性问题提供技术依据。【方法】选用3种浓度的石蜡乳液(0.5%,1%和2%)与2种浓度的CA防腐剂(0.3%和0.5%)进行复配,利用满细胞法一次性处理尺寸为19 mm( T)×38 mm( R)×89 mm( L)的美国南方松边材,计算处理材的增重率和铜的载药量,并参照美国木材保护协会标准AWPA E12-08对304不锈钢、热镀锌钢、Q235A钢3种金属的金属腐蚀性进行测试。【结果】1) CA单独处理材中铜的载药量分别为(1.81±0.12)和(3.800.03)kg·m -3,达到预设防腐等级C3(≥1.7 kg·m -3)和C4A(≥3.3 kg·m -3)的载药量要求;2)腐蚀后的金属表面,Q235A钢被腐蚀最严重,表面有大量附着红色的铜单质,热镀锌钢有轻微腐蚀,304不锈钢基本不被腐蚀;3)各组处理材对304不锈钢的金属腐蚀率均为0;CA单独处理材对 Q235A 钢的金属腐蚀率为素材的2~3倍,添加石蜡乳液防水剂后复配处理材的金属腐蚀率明显降低;处理材对于热镀锌钢的腐蚀规律与 Q235A钢相似,但腐蚀率小很多。【结论】1)处理材对3种金属的腐蚀程度为 Q235A钢>热镀锌钢>304不锈钢;2) CA 防腐剂会加剧处理材对 Q235A钢和热镀锌钢的腐蚀;单独石蜡乳液防水剂处理材对 Q235A 钢的腐蚀略比素材低,对热镀锌钢的腐蚀与素材无明显差别;3)在CA防腐剂中添加石蜡乳液防水剂可以明显降低CA处理材对Q235A钢和热镀锌钢的腐蚀,且随着石蜡乳液浓度的增大,处理材的金属腐蚀率减小。
王佳敏马尔妮曹金珍
关键词:木材复配
木粉/聚丙烯复合材料耐光老化性调控机理研究
为改善木塑复合材料的耐光老化性能,延长材料的使用寿命,本研究以毛白杨木粉(WF)和聚丙烯(PP)为原料,制备木粉/聚丙烯(WF/PP)复合材料为研究对象。在老化机理方面,对WF的组成成分进行分离,着重探讨了复合材料中木质...
彭尧
关键词:非金属复合材料木粉聚丙烯
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初始含水率对SiO_2溶胶在两种木材中渗透性的影响被引量:2
2015年
采用两种粒径(30nm和150 nm)的Si O2溶胶真空浸渍不同含水率(绝干、气干、调湿)的欧洲赤松和南方松边材,比较其24 h内吸液率变化规律和24 h增重率,并通过质量法分析硅溶胶处理材轴向SiO2的浓度梯度,从而考察处理材的初始含水率对SiO2溶胶在木材中渗透性的影响。研究结果表明:(1)两种木材均在绝干状态下吸液率最低,30 nm硅溶胶在气干状态下吸液率最高,而150 nm硅溶胶在调湿状态下吸液率最高。(2)初始含水率对增重率的影响与吸液率不同,30 nm硅溶胶在调湿状态下浸渍木材的增重率低于绝干状态,欧洲赤松气干状态的增重率最高。(3)初始含水率对试材中整体SiO2量的影响与增重率结果基本一致,欧洲赤松中SiO2轴向分布梯度远高于南方松,其渗透的均匀性较差。
孙敏洋曹金珍
关键词:木材SIO2溶胶渗透性初始含水率
蒙脱土处理木纤维的表面性状及吸湿性
2014年
采用钠基蒙脱土(Na-MMT)和季铵盐(DDAC)两步处理法改性木纤维,并检测改性纤维的吸湿性、接触角,并对其结构、基团变化、形态进行表征分析。结果表明:改性纤维的吸湿率降低,接触角增加;Na-MMT与DDAC在木纤维内部反应生成OMMT,在纤维细胞壁形成有效插层,且与纤维中的化学组分发生结合。为纤维板尺寸稳定处理提供一种新方法。
欧阳靓曹金珍罗文圣
关键词:木纤维钠基蒙脱土有机蒙脱土改性吸湿性
SiO2溶胶在欧洲赤松和火炬松边材中的渗透性被引量:4
2015年
为了考察微纳米液体改性剂在木材中的渗透规律,采用2种粒径(30和150 nm)和3种浓度(质量分数5%,15%、30%)的SiO2溶胶真空30 min-常压浸渍24 h欧洲赤松和火炬松边材,比较其24 h内吸液率的经时变化规律和24 h增重率,通过质量法分析30nm、15%的硅溶胶处理材轴向SiO2的浓度梯度,并采用扫描电镜-X射线能谱仪分析各轴向深度木材细胞壁中硅元素的分布。结果表明:1)粒径小的硅溶胶在浸渍初期更易于在木材中渗透,随着浸渍时间的延长,粒径的影响变小,甚至可能出现相反的趋势;浓度对吸液率影响显著,一般浓度越高,吸液率越小。浓度高的改性剂处理木材时,粒径的影响更为显著。2)树种对硅溶胶的渗透性影响显著。硅溶胶在欧洲赤松边材的吸液率通常高于火炬松边材,但由于硅溶胶颗粒和水分在欧洲赤松中渗透不同步,硅溶胶在端头部分的大量沉积,导致欧洲赤松中SiO2在轴向分布浓度梯度远高于火炬松。3)硅元素进入各个轴向深度的木材细胞壁,硅元素的浓度分布规律与质量法结果一致。
孙敏洋曹金珍
关键词:木材SIO2溶胶渗透性粒径
CA-B /New-type Paraffin Emulsion Compound System: Study on the Mould Preservation Property of Treated Wood被引量:1
2014年
[Objective] The aim was to develop the compound system of paraffin emulsion and CA based on natural surfactants to improve the properties of anti- mould and anti-blue stain. [Method] The paraffin wax emulsion with different con- centrations of 0.5%, 1.0% and 2.0% was added into CA (0.3% and 0.5%) to obtain six groups of compound systems. The full-cell process was applied to treat the sapwood of Pinus spp. at size of 50 mm (L)×20 mm (R)×5 mm (T). Anti-mould and anti-blue stain tests were conducted using Botryodiplodia theobromae Pat., Spergi/lus niger V. Tiegh and Trichoderma viride Pers.ex Fr. according to the GB/T18261-200. [Result] Both paraffin wax emulsion and CA-B could prevent wood against mould and blue stain. However, within a certain range, anti-mould and anti-blue stain ef- fects of wood samples treated by the compound systems reduced slightly as the concentration of paraffin wax emulsion increased. [Conclusion] The research provides references for advancing use of wood biomass resources in a more efficient and more environment-friendly way.
钟卉王佳敏汤少怀马尔妮
关键词:WATERPROOF
Stress Relaxation of Paraffin Wax Emulsion/Copper Azole Compound System Treated Wood
2016年
[Objective] An approach of stress relaxation was proposed in present work to investigate the interactions among the waterproof agent,preservative and wood.[Method] Paraffin emulsion waterproof using natural surfactants was prepared at different concentrations of 0.5% and 2.0%,which were added into two concentrations(0.3%,0.5%) of copper azole(CA) to obtain compound systems,and one-time fullcell process was applied to treat the sapwood of Pinus spp.with a size of 10 mm(L) ×10 mm(R) ×10 mm(T).[Result] Compressive stress relaxation behaviors at two moisture levels and room temperature were measured and the results were as follows:1) compared with control group,the stress relaxation of compound system treated groups reduced,whether at oven-dried state or air-dried state.2) Under oven-dried condition,CA could weaken the relaxation of treated samples and this effect became greater with increasing concentration of preservative,but an increase in the concentration of paraffin emulsion would slightly promote the relaxation of compound system treated samples.While under air-dried condition,both CA and paraffin wax emulsion lowered the relaxation which was inversely related to the concentrations of both agents.[Conclusion] The results were expected to shed new light on the various macroscopic properties of the compound system treated wood at a microscopic level,and to provide favorable scientific evidences and theoretical supports for the manufacture of waterproofing preservative-treated wood.
廖雨晴钟卉马尔妮
关键词:WOODWATERPROOFPRESERVATION
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