The research on electroluminescence based on europium(Ⅲ) complexes has come to an important phase. This article reviewed the progresses in photoluminescence and electroluminescence of Eu(Ⅲ) complexes in recent years from the views of the design of Eu(Ⅲ) com-plexes and optimization of device structures,and discussed some important factors influencing electroluminescence performance. The prob-lems existing in the practical application such as the volatility and thermal stability of Eu(Ⅲ) complexes in this area were discussed,and the possible corresponding solutions were briefly prospected.
Bipyrimidines have been chosen as(N^N)(N^N) bridging ligands for connecting metal centers.IrⅢ-LnⅢ(Ln = Nd,Yb,Er) bimetallic complexes [Ir(dfppy)2(μ-bpm)Ln(TTA)3]Cl were synthesized by using Ir(dfppy)2(bpm)Cl as the ligand coordinating to lanthanide complexes Ln(TTA)3·2H2O.The stability constants between Ir(dfppy)2(bpm)Cl and lanthanide ions were measured by fluorescence titration.The obvious quenching of visible emission from IrⅢ complex in the IrⅢ-LnⅢ(Ln = Nd,Yb,Er) bimetallic complexes indicates that energy transfer occurred from IrⅢ center to lanthanides.NIR emissions from NdⅢ,YbⅢ,and ErⅢ were obtained under the excitation of visible light by selective excitation of the IrⅢ-based chromophore.It was proven that Ir(dfppy)2(bpm)Cl as the ligand could effectively sensitize NIR emission from NdⅢ,YbⅢ,and ErⅢ.
CHEN FangFang,JIANG WeiLi,LOU Bin,BIAN ZuQiang & HUANG ChunHui Beijing National Laboratory for Molecular Sciences,State Key Laboratory of Rare Earth Materials Chemistry and Applications,College of Chemistry and Molecular Engineering,Peking University,Beijing 100871,China
