A series of photosensitive random copolymers (UPDHES) were prepared by introducing acrylate groups onto the side chain of the copolymer backbone of N, N-domethyl amimethyl methacrylate (DMAEMA), 2-hydroxypropyl acrylate (HEA), 2-ethylhexyl acrylate (EHA), and styrene (St) (PDHES). The molecular structure of UPDHES was characterized by FTIR, 1HNMR and GPC. The photopolymerization kinetics of UPDHES with different C=C content was investigated using real time FTIR in which it was found that the UPDHES system had notable photosensitivity. The effect of C=C content on the properties of cured films were studied by evaluating various film properties such as thermal stability, glass transition temperature and tensile properties. The thermal degradation of cured films was investigated via thermogravimetric analysis/infrared spectrometry (TGA-IR). Thus a series of UV-curable electrodeposition coatings with good photosensitivity and mechanical properties were prepared from a low-cost photosensitive random copolymer.
