The bilayer compounds[n-CnH2n+1N(CH3)3]2Zn Cl4(n=16,18)experience solid-solid phase transition within the temperature range of 310 to 340 K.The low-temperature crystal structures of the pure compounds are characteristic of the piling effect in which a 2D macro-anion Zn Cl42- is sandwiched between two alkylammonium layers.These layers become conformationally disordered in the high-temperature phases.The structures can alternatively be viewed as a double layer of alkylammonium ions between Zn Cl42- sheets and can be considered as crystalline models of lipid bilayers.The experimental subsolidus binary phase diagram of[n-C16H33N(CH3)3]2Zn Cl4-[n-C18H37N(CH3)3]2Zn Cl4 has also been established over the whole composition range by differential scanning calorimetry(DSC)and X-ray diffraction.In the phase diagram,one intermediate compound[n-C16H33N(CH3)3][n-C18H37N(CH3)3]Zn Cl4 at WC16C3Zn%47.50 and two eutectoid invariants points at WC16C3Zn%35.10 and75.70 were observed;the respective temperatures of the two eutectoids are 320±1 and 315±1 K.In addition,there are three noticeable solid solution ranges in the phase diagram:α-phase at the left,β-phase at the right,andγ-phase in the middle.
RUAN BeiWU Ke ZhongCHEN JingXIONG Yuan YuanREN Bi Yan
Compounds [n-CnH2n＋1N（CHs）3]2CoCl4（n=16, C46C3Co; n=18, C18C3Co） containing lipid-like bilayers embedded in a crystalline matrix exist in solid-solid phase transition. The low-temperature bilayer structures of the two compounds were organized by neutralizing CoCl24- with alkylammonium ions. Alkyl chains lay parallel to each other and slightly tilted with respect to the normal of the inorganic layers. The adjacent alkyl chains interacted with each other by van der Waals interaction. When the temperature increased, the two compounds underwent a reversible solid-solid phase transformation within 310-330 K. In such a case, the chains showed a large motional freedom, and a disordered phase appeared. The structures can alternatively be viewed as a double layer of alkylammonium ions between COCl24- sheets and be considered as crystalline models of lipid bilayers. The experimental subsolidus binary phase diagram of [n-C16H33N（CH3）3]2CoCl4-[n-C18H37N（CH3）3]2CoCl4 was constructed over the entire composition range by differential scanning calorimetry and X-ray diffraction technique. Experimental phase diagram indicates one stable intermediate phase [n-C16H33N（CH3）3][n-C18H37N（CH3）3]CoCl4 at wC16C3Co = 39.89% and two invariant three-phase equilibria, which shows two eutectoid temperatures： Te1 at （316±1） K for WC16C3Co=27.35% and Te2 at （313±1）K for Wc16c3co =59.76%. These three noticeable solid-solution ranges are a-phase at the left, β-phase at the right, and γ-phase in the middle of the phase diagram.
WU Kezhong SUN Xiaolong RUAN Bei XIONG Yuanyuan CHEN Jing
