The chemical composition and aluminum speciation of sludge incineration residue (SIR) were determined. Cementation of aluminum from sulfuric acid solution using SIR was studied. The results showed that acid-soluble inorganic aluminum was the predominant component in the sludge, and the total leached aluminum increased from 62.2% to 92.9% after incineration. Sulfuric acid dosage and reaction time were found to affect aluminum recovery positively. Conversely, the increase in temperature significantly inhibited recovery reactions. The optimized leaching condition was 1.66 g sulfuric acid per gram of SIR with a reaction time of 3 hr at 20°C, resulting in the highest aluminum leaching rate of 96.7%. Compared to commercial aluminum sulfate solution coagulants, the leaching solution demonstrated higher CODCr, turbidity and color removal efficiency for textile wastewater.
Objective This study was conducted to optimize the operational parameters of anaerobic-anoxic-oxic (A2/O) processes to reduce the toxicity of municipal wastewater and evaluate its ability to reduce toxicity.Methods A luminescent bacterium toxicity bioassay was employed to assess the toxicity of influent and effluent of each reactor in the A2/O system.Results The optimum operational parameters for toxicity reduction were as follows:anaerobic hydraulic retention time (HRT)=2.8 h,anoxic HRT=2.8 h,aerobic HRT=6.9 h,sludge retention time (SRT)=15 days and internal recycle ratio (IRR)=100%.An important toxicity reduction (%) was observed in the optimized A2/O process,even when the toluene concentration of the influent was 120.7 mg·L-1.Conclusions The toxicity of municipal wastewater was reduced significantly during the A2/O process.A2/O process can be used for toxicity reduction of municipal wastewater under toxic-shock loading.
