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国家自然科学基金(20971032): 作品数：3 被引量：3H指数：1; 相关作者：王路周百斌更多>>; 相关机构：哈尔滨工业大学哈尔滨师范大学更多>>; 发文基金：国家自然科学基金黑龙江省博士后基金黑龙江省自然科学基金更多>>; 相关领域：理学医药卫生更多>>

One novel hybrid compound based on[AlW12O40]5- heteropolyanions and cobalt coordination polymer with in situ ligand:tetradentate N-heterocyclic ligand: Under hydrothermal condition,one novel organic inorganic hybrid compound,[Co（Htpybenz）2][AlW12O40]H2O （1）（tpyb...; Ying Chen; 文献传递

抗癌多金属氧酸盐被引量：2: 2013年; 多金属氧酸盐具有独特的结构特征及优良的理化性能,已引起国内外科技工作者极大的兴趣与关注,特别是多金属氧酸盐作为抗癌化疗药物的研究,更成为本领域科学研究的前沿之一。本文综述了多金属氧酸盐作为抗癌生物活性药物的国内外研究进展,其内容主要包括多金属氧酸盐抗癌作用依据,同多、杂多金属氧酸盐不同结构类型的体外抗癌作用、体内抗癌作用及其抗癌作用机制等,提出了多金属氧酸盐抗癌研究应重点解决的几个问题,为进一步研究多金属氧酸盐抗癌药物活性提供了参考。; 王路周百斌刘家仁; 关键词：多金属氧酸盐抗癌生物活性化疗药物

The Two-electron reduced Basket-like[SrP6MoⅤ4MoⅥ14O73]8- Polyoxoanion Modified with {Ni（4,4’-bipy）（H2O）3} complex: A new basket-like mixed-valent compounds [H2（4,4’-bipy ）]5 {[Ni（4,4’-bipy）（H2O）3]2 [Ni（H2O）2]}[Sr（?）P6Mo2ⅤMo6Ⅵ...; Kai Yu~(a; 文献传递

Syntheses,Crystal Structures and Electrochemical Properties of Two Molybdophosphates被引量：1: 2010年; Two molybdophosphate compounds,[Ni(bim)3]2[H2P2Mo5O23]·2H2O 1 and [Zn(bpy)2]2[Zn(bpy)(H2O)]2Zn[Mo6O12(OH)3(HPO4)4]2·9H2O 2 (bim = 2,2'-biimidazole,bpy = 2,2'-dipyridyl),have been synthesized under hydrothermal conditions and structurally characterized by elemental analysis,TG,and IR. The single-crystal X-ray analysis exhibits that 1 consists of one [H2P2Mo5O23]4-,two [Ni(bim)3]2+ cations and two lattice water molecules,while 2 is constructed from one sandwich-type [ZnP4Mo6] anion modified by four Zn-bpy complexes and nine lattice water molecules. The electrochemical behaviors of compounds 1 and 2 have been studied in detail based on solid bulk modified carbon paste electrodes of compound (CPEs).; 于洋于凯周百斌赵志凤苏占华; 关键词：钼化合物修饰碳糊电极水热条件 X射线分析

Synthesis,structure and property of heteroatom-"embedded" X{P6Mo18O73} basket-like cluster cage modified with {Cu（2,2’-bpy）（H2O）} fragments: A family of new organic-inorganic hybrid polyoxometalate based on basket-like mixed-valent polymolybdophosphat...; Bin Wan; 文献传递

Polyoxometalates crystals synthesis and properties on catalytic preparation ethylene glycol: The synthesis of new polyoxometalates(POMs) crystal is the main branch of chemistry[1].POMs,as environmently-f...; Zhan-Hua Su~a; 文献传递

Ultrasonic synthesis of Cu2O nanostructures at room temperature and photoluminescent properties: Shape-controlled synthesis of Cu2O nanostructures has been achieved in the ultrasonic method at room temperatu...; Zeng-ming qin; 文献传递

含钴多酸对人肿瘤细胞抑制作用研究: <正>本文合成表征了药物配体咪唑修饰的含钴多酸(H2imi)2[Bi2W20O70Co2(H2O)6Na4(H2O)14]·2H3O·15H2O1,并研究其对人肿瘤细胞生长抑制活性。采用MTT法,细胞形态学分析,单细胞凝...; 王路张思琪初丽丽周百斌; 关键词：人肿瘤细胞钴; 文献传递

含黄胺配体多酸合成、晶体结构及体外抗肿瘤作用: <正>本文合成了含有磺胺配体的Keggin型多金属氧酸盐[{K(C6H10N2O2S)2(H2O)}2(SiW12O40)2]·2H3O+·10H2O(1),并通过元素分析、IR、TG、XPS、183WNMR和单晶X-射...; 王路张思琪吴江周百斌; 关键词：体外磺胺抗肿瘤; 文献传递

Two-Dimensional layer paradodecatungstate by in aqueous solution synthesis:[{Cu0.5（H2O）}2{Cu0.5（H2O）2}2 {Cu（bim）（H2O）2}2(H4W12O42)]·10H2O: A novel polyoxotungstate, [{Cuo5（H2O）}2{Cu0.5（H2O）2}2{Cu（bim）（H2O）2}2(H4W12O42)]·1 0H2O 1,（bim = 2,2’-biimidaz...; Song Gao; 文献传递

国家自然科学基金(20971032)