The volumetric mass transfer coefficient kLa of gases(H2, CO, CO2) and mass transfer coefficient kLon liquid paraffin side were studied using the dynamic absorption method in slurry bubble column reactors under elevated temperature and elevated pressure. Meanwhile, gas-holdup and gas–liquid interfacial area a were obtained.The effects of temperature, pressure, superficial gas velocity and solid concentration on the mass transfer coefficient were discussed. Experimental results show that the gas–liquid volumetric mass transfer coefficient kLa and interfacial area a increased with the increase of pressure, temperature, and superficial gas velocity, and decreased with the slurry concentration. The mass transfer coefficient kLincreased with increasing superficial gas velocity and temperature and decreased with higher slurry concentration, while it changed slightly with pressure. According to analysis of experimental data, an empirical correlation is obtained to calculate the values of kLa for H2(CO, CO2) in the gas–paraffin–quartz system in a bubble column under elevated temperature and elevated pressure.
Based on the principle of chemical reaction engineering,the addition of perforated plates can improve the performance of conventional bubble column and decrease the backmixing behaviors.The distribution characteristics of gas holdup in a multi-stage bubble column embedded with five types of sieve plates and three types of tongue plates were studied using electrical resistance tomography(ERT).The effects of superficial gas velocity and the geometric design of perforated plates on the gas holdup and its radial distribution above and below the plates of the bubble column were discussed.Experimental results show ERT is suitable as an online monitoring tool to provide useful information on the hydrodynamic parameters of multi-stage bubble columns.With increasing superficial gas velocity,local gas holdup increases,and gas holdup below the plate increases with decrease of free area(%FA),hole diameters or angle of tongue plates.ERT technique facilitates noninvasive and nonintrusive visualization of cross-sectional distribution of gas holdup in a bubble column.
Haibo JinYicheng LianYujian QinSuohe YangGuangxiang He
