The efficient Eu2+ -doped Ba3 Si6O12N2 green phosphors were prepared by a traditional solid state reaction method under N2 /H2 atmosphere at a temperature up to 1350 oC for 12h. Photoluminescence (PL) properties showed a broad emission band with a peak of 525 nm and the full width of half-emission maximums (FWHM) of 70 nm under 460 nm light irradiation. The X-ray diffraction patterns (XRD) and scanning electron microscope (SEM) images of the synthesized powder demonstrated its pure phase and excellent crystallization. Quenching concentration in this phosphor was found to be 0.3. The mechanisms of concentration quenching and redshift of emission peak with increasing concentration of Eu2+ were studied. The temperature dependence measurement of this green phosphor revealed excellent thermal quenching property compared to silicate green phosphor. It is believed that Ba3 Si6O12N2 :Eu2+ is an excellent green phosphor for UV or blue chip based white LEDs.
Monodisperse(Sr,Eu)CO3 sphere(the homogenous mixture of Sr2+ and Eu3+ carbonates) was firstly prepared,and then its surfacewas coated by amorphous SiO2 in the presence of cationic surfactant cetyltrimethylammonium bromide(CTAB) to form(Sr,Eu)CO3@SiO2core-shell-like precursor.The overall synthesized mechanism was investigated and proposed based on the Fourier transform infrared spectroscopy(FTIR),X-ray diffraction(XRD) and scanning electron microscopy(SEM).This strategy could be applied to construct core-shellstructured precursors for the preparation of alkali earth silicate phosphors.
