在新型扭动微动试验机上,进行聚甲基丙烯酸甲酯(PMMA)与Ф40 mm GCr15钢球在扭动角位移幅值为0.5°~10°和法向载荷为100N的扭动微动试验。在摩擦动力学行为研究的基础上,分析材料磨损机理。结果表明,PMMA存在有平行四边形和椭圆两种T-θ曲线;低扭转角时,T-θ曲线随着循环次数的增加从平行四边形向椭圆形发展;大扭转角时,T-θ曲线始终为平行四边形。PMMA的扭动微动磨痕沿半径方向,可依次分为粘着区、微裂纹区和剥落区。在低角位移幅值(θ≤2.5°)时,扭动微动损伤较轻微;随角位移幅值的增大,粘着区变小,损伤加重,表面出现纺锤状剥落坑自中心呈放射状分布,其尺寸随角度增大而变宽。对磨屑的GPC分析结果表明PMMA在扭动微动条件下分子量变小,PMMA扭动微动的磨损机理主要为剥落与表面裂纹。
Micro-arc oxidation(MAO)coating was prepared on Ti6Al4V alloy surface and its characterizations were detected by Vickers hardness tester,profilometer,scanning electric microscope(SEM),energy dispersive X-ray spectrometer(EDX)and X-ray diffractometer(XRD).Fretting wear behaviors of the coating and its substrate were comparatively tested without lubrication under varied displacement amplitudes(D)in a range of 3-40μm,constant normal load(Fn)of 300 N and frequency of 5 Hz.The results showed that the MAO coating,presenting rough and porous surface and high hardness,mainly consisted of rutile and anatase TiO2 phases.Compared with the substrate,the MAO coating could shift the mixed fretting regime(MFR)and slip regime(SR)to a direction of smaller displacement amplitude.In the partial slip regime(PSR),lower friction coefficients and slight damage appeared due to the coordination of elastic deformation of contact zones.In the MFR,the friction coefficient of the coating was lower than that of the substrate as a result of the prevention of plastic deformation by the hard ceramic surface.With the increase of the displacement amplitude,the degradation of the MAO coating and the substrate increased extremely.The fretting wear mechanisms of the coating were abrasive wear and delamination with some material transfer of specimen.In addition,the coating presented a better property for alleviating fretting wear.
