Size-dependence of optical properties and energy relaxation in CdSe/ZnS quantum dots (QDs) were investigated by two-colour femtosecond (fs) pump-probe (400/800 nm) and picosecond time-resolved photoluminescence (ps TRPL) experiments.Pump-probe measurement results show that there are two components for the excited carriers relaxation,the fast one with a time constant of several ps arises from the Auger-type recombination,which shows almost particle sizeindependence.The slow relaxation component with a time constant of several decades of ns can be clearly determined with ps TRPL spectroscopy in which the slow relaxation process shows strong particle size-dependence.The decay time constants increase from 21 to 34 ns with the decrease of particle size from 3.2 to 2.1 nm.The room-temperature decay lifetime is due to the thermal mixing of bright and dark excitons,and the size-dependence of slow relaxation process can be explained very well in terms of simple three-level model.
