The Er Al2@Al2O3 nanocapsules with Er Al2core and Al2O3 shell were synthesized by modified arc-charge technique.The typical core-shell structure of the nanocapsules was confirmed by high resolution transmission electron microscopy and X-ray photoelectron spectroscopy.Transmission electron microscopy analysis shows the irregular sphere of the nanocapules with an average diameter of 26 nm.Magnetic investigation revealed the Curie temperature of Er Al2@Al2O3 nanocapsules at 20 K and the typical superparamagnetic behavior between blocking temperature and Curie temperature.Based on the blocking temperature and average diameter,the magnetocrystalline anisotropy constant of Er Al2@Al2O3nanocapsules was estimated to illustrate the magnetic contribution to the-SM.The large-SMof 14.25 J/（kg K）was obtained under 50 k Oe at 5 K.A vital parameter β was introduced in the present work to scale the optimized magnetic characteristics and the optimized mechanism was discussed in detail according to classical superparamagnetic theory.The results demonstrate that the optimal-SMwill be obtained when the magnetic parameter β is close to the theoretical coefficient.
Skyrmions are very promising for applications in spintronics and magnetic memory.It is desired to manipulate and operate a single skyrmion.Here we report on the thermal effect on the motion of current-driven magnetic Skyrmions in magnetic metal.The results show that the magnon current induced by the thermal gradient acts on Skyrmions via magnonic spin-transfer torque,an effect of the transverse and longitudinal Skyrmions drift velocities,thus leading to the effective manipulation of the Hall angle through the ratio of thermal gradient to electric current density,which can be used as a Skyrmion valve.
In this review article, the recent experimental and theoretical research progress in Bi2Se3-and Bi2Te3-based topological insulators is presented, with a focus on the transport properties and modulation of the transport properties by doping with nonmagnetic and magnetic elements. The electrical transport properties are discussed for a few different types of topological insulator heterostructures, such as heterostructures formed by Bi2Se3-and Bi2Te3-based binary/ternary/quaternary compounds and superconductors, nonmagnetic and magnetic metals, or semiconductors.
We use the first-principles calculation method to study the interface effect on the structure and electronic properties of graphdiyne adsorbed on the conventional substrates of rough SiO2 and flat h-BN. For the SiO2 substrate, we consider all possible surface terminations, including Si termination with dangling bond, Si terminations with full and partial hydrogenation, and oxygen terminations with dimerization and hydrogenation. We find that graphdiyne can maintain a flat geometry when absorbed on both h-BN and SiO2 substrates except for the Si termination with partial hydrogenation（Si-H） SiO2 substrate. A lack of surface corrugation in graphdiyne on the substrates, which may help maintain its electronic band character, is due to the weak Van der Waals interaction between graphdiyne and the substrate. Si-H SiO2 should be avoided in applications since a covalent type bonding between graphdiyne and SiO2 will totally vary the band structure of graphdiyne.Interestingly, the oxygen termination with dimerization SiO2 substrate has spontaneous p-type doping on graphdiyne via interlayer charge transfer even in the absence of extrinsic impurities in the substrate. Our result may provide a stimulus for future experiments to unveil its potential in electronic device applications.
Carbon-coated Cu nanocomposites (Cu@C NCs) consisting of core-shell nanoparticles and nanorods weresynthesized by arc discharge plasma under an atmosphere of He and H_(2) gas, and the N-doping of themwas achieved by a post-treatment process using ureal as the precursor. The concentration of N in the Ndoped samples varies in the range of 0.62%-2.31 % (in mole), with a transformation from pyrrolic N tographitic N when increasing the relative content of ureal. Dielectric properties of the NCs without or withN-doping in the microwave and THz bands were investigated. The N-doped samples achieve theenhanced dielectric loss in both microwave and THz bands. In the microwave band, dielectric loss wasdominated by interfacial polarization, dipolar polarization, and conduction loss, while in the THz band,plasma resonance, ionic polarization and conduction loss are responsible for the dielectric loss, with astrong absorption characteristic dominated by conductive effect.
Experimental and theoretical researches on nanostructured exchange coupled magnets have been carried out since about 1988. Here, we review the structure and magnetic properties of the anisotropic nanocomposite soft/hard multilayer magnets including some new results and phenomena from an experimental point of view. According to the different component of the oriented hard phase in the nanocomposite soft/hard multilayer magnets, three types of magnets will be discussed：1） anisotropic Nd2Fe（14）B based nanocomposite multilayer magnets, 2） anisotropic SmCo5 based nanocomposite multilayer magnets, and 3） anisotropic rare-earth free based nanocomposite multilayer magnets. For each of them, the formation of the oriented hard phase, exchange coupling, coercivity mechanism, and magnetic properties of the corresponding anisotropic nanocomposite multilayer magnets are briefly reviewed, and then the prospect of realization of bulk magnets on new results of anisotropic nanocomposite multilayer magnets will be carried out.
