With the help of high-energy mechanical milling and α-SiO2 as the initial material, we investigated the synthesis of coesite at a high temperature and high pressure under the condition of adding a certain amount of hard Fe filling. The synthetic samples were measured by XRD and Raman spectroscopy. The results show that a small amount of small-sized coesite can be obtained under 2.5 GPa and 973 K.
WANG De-junLIU Xiao-meiZHU Cheng-junYAN Duan-tingLIU Fu-linSU Wen-hui
The mixtures of α-quartz and graphite powder with different mass ratios were, respectively, high-energetically mechanically milled and then treated under high pressure and high temperature. The influences of carbon content on the synthesis conditions of coesite were investigated. The experimental products were characterized by XRD, TEM, and Raman spectrometry. The results show that the existence of carbon can obviously inhibit the formation of coesite, and the higher the carbon content of the initial material, the higher the pressure for forming coesite.
WANG De-junLIU Xiao-meiZHU Cheng-junYAN Duan-tingLIU Yi-xinSUN YingLIU Fu-linSU Wen-hui
