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国家自然科学基金(81071256)

作品数:6 被引量:3H指数:1
相关作者:戴耀东李俊魏少强代明珠孙浩更多>>
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发文基金:国家自然科学基金中央高校基本科研业务费专项资金国家教育部博士点基金更多>>
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单壁碳纳米管的γ辐射剪切与光声效应被引量:1
2011年
系统研究了在硫酸溶液中用γ辐射法剪切单壁碳纳米管,初步探索了在激光以及γ射线照射下的水溶液中单壁碳纳米管的光声效应,并对辐射剪切单壁碳纳米管的机制进行了讨论。用透射电子显微镜(TEM)、傅里叶变换红外光谱(FT-IR)以及拉曼光谱对短单壁碳纳米管进行分析和表征。结果表明:γ辐射和硫酸氧化作用在剪切碳管的过程中存在协同效应,得到的短碳纳米管的平均长度为200~400nm,在水中可稳定分散1周;辐射剪切在碳纳米管外侧及端帽处引进—OH、—COOH等官能团。另外,Q开关脉冲激光照射下的单壁碳纳米管在溶液中会发生强光声效应,相比而言,当照射碳管的光子能量达到γ光子能量时碳管的光声效应非常微弱。
孙浩余健开马南茹魏少强戴耀东
关键词:单壁碳纳米管Γ辐射剪切光声效应
Effects of WO_(3) Particle Size in WO_(3)/Epoxy Resin Radiation Shielding Material被引量:1
2012年
To verify the influence of the functional elements particular size for the radiation attenuation coefficients and mechanical properties radiation shielding material based on epoxy resin,we prepare two WO_(3)/E44 samples with different particular sizes of WO_(3) by a solidified forming approach.The linear attenuation coefficients of these samples are measured forγ-ray photo energies of 59.6,121.8,and 344.1 keV,etc.using narrow beam transmission geometry.It is found that the linear attenuation coefficients would increase with the decreasing particle size of the WO_(3) in the epoxy resin based radiation shielding material.The theoretical values of the linear attenuation coefficients and mass attenuation are calculated using WinXcom,and good agreements between the experimental data and the theoretical values are observed.From the studies of the obtained results,it is reported that from the shielding point of view the nano-WO_(3) is more effective than micro-WO_(3) in the epoxy resin based radiation shielding material.
董宇常树全张红旭任超康斌代明珠戴耀东
关键词:MATERIALRESIN
Surface plasmon resonance scattering and absorption of biofunctionalized gold nanoparticles for targeted cancer imaging and laser therapy
2011年
The localized surface plasmon resonance of gold nanoparticles enables them to be excellent light scattering sensing reagents and efficient lignt-heat convertors for potential diagnostics and therapeutics.In this work,gold nanoparticles of 15 nm in size were synthesized and conjugated with a kind of arginine-glycine-aspartic acid peptide(RGD)to target the cancer cells.Under a conventional dark field microscope,the scattering images from normal and cancer cells are very different.Only a few of gold nanoparticles bind to the membrane of normal cells due to nonspecific interaction.Yet for cancer cells,the concentration of gold nanoparticles inside cancer cells is much higher than that inside normal cells,showing a strong light scattering signal.By exposing these cells to an external laser irradiation,cancer cells were selectively destructed because of the heat conversion of gold nanoparticles inside them,but normal cells still kept alive due to the absence of gold nanoparticles in them.These results incidated that gold nanoparticles might be potential contrast reagents for targeted cancer imaging and laser therapy.
GE YunKANG Bin
关键词:表面等离子体共振金纳米粒子光散射正常细胞
热分解法制备多壁碳纳米管负载铁氧体纳米粒子复合材料被引量:1
2014年
以乙酰丙酮铁作为铁源,三甘醇作为溶剂,采用热分解法制备了原始以及酸化后的多壁碳纳米管负载铁氧体纳米粒子的复合材料。并用扫描电子显微镜(TEM)、X射线衍射(XRD)、穆斯堡尔谱等分析了材料的微观结构和特性。结果表明,铁氧体纳米粒子均匀地修饰在碳纳米管表面,没有明显团聚现象产生,酸化后的碳纳米管表面生成的纳米粒子中包含了Fe3O4与Fe2O3两种粒子。碳纳米管经酸化后,其表面生成了许多缺陷,缺陷处的活泼电子更容易与生成的Fe3O4纳米粒子的外层电子之间进行快速的电子交换,使得Fe3O4纳米粒子中的FeⅡ被部分氧化,使生成的铁氧体纳米粒子更多地表现为Fe2O3的特性。
李俊代明珠戴耀东
关键词:纳米复合材料热分解法碳纳米管铁氧体纳米粒子
亚铁氰化锌对放射性废水中铜离子的吸附研究
2014年
采用共沉淀法制备了一种普鲁士蓝类似物——亚铁氰化锌(KZnFC),通过X射线荧光分析仪(XRF)和X射线衍射仪(XRD)表征分析,确定样品化学组成式为K1.11Zn1.53Fe(CN)6。采用静态吸附研究了亚铁氰化锌在不同吸附时间、用量、pH值、铜离子初始质量浓度条件下对模拟放射性废水硫酸铜溶液中铜离子的吸附影响,并通过透射电镜(TEM)和穆斯堡尔谱分析对吸附机理进行了初步探讨。实验结果表明:亚铁氰化锌对Cu外在用量为100mg、pH值为4~7、室温等条件下,2h内去除率可达89.23%,吸附量可达121.86mg/g。KZnFC对Cu2+吸附前后的穆斯堡尔谱表明,此吸附过程主要是KZnFC中的K+同溶液中Cu2+进行离子交换反应。亚铁氰化锌对铜离子的吸附过程符合Freundlich吸附等温模型。
龙清康斌戴耀东李俊
关键词:铜离子放射性废水
A novel cerrobend block in the radiation therapy
2012年
This study was carried out to look for the substitute products of lead cerrobend block and determine whether the products can give more radiation dose to the tumor in the skin and superficial tumors in radiotherapy treatment.Five kinds of PbO/Er2O3/Epoxy(E-51) samples used as the cerrobend block in the electron beam radiotherapy treatment were prepared success-fully by a solidified forming approach.The central axis depth dose and off-axis dose profiles in the water phantom were calcu-lated using BEAMnrc/DOSEXYZnrc user codes.The results revealed that there were more energy deposition events induced by low energy electron beams in the surface of the water phantom.These electron beams were attributed to Compton scattering and photoemission between photons and erbium,plumbum elements.The maximum dose(Dm) and the depth at the maximum dose(Rm) were linearly dependent on the mass fraction of erbium and plumbum element in the sample.The max dose and its depth varied depending on the combined actions of new electrons and transmission electrons.
CHANG ShuQuanZHANG YuDONG YuZHANG HongXuDAI YaoDong
关键词:放射疗法
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