Herein, we prepared a series of H-Zn-mordenite (H-Zn-MOR) catalysts by adding zinc source into the initial sols during the synthesis of mordenite (MOR). The results indicated that isolated Zn ions were highly dispersed in the catalysts. The addition of zinc led to the increase of Si/Al in the framework of MOR,the change of the distribution of acid sites and the change of acid strength. We investigated the catalytic performance of the H-Zn-MOR catalysts and the HMOR catalysts for carbonylation of dimethyl ether to methyl acetate. The addition of zinc improved the catalytic performance and made the drop of the conversion over the Zn-0.003 and Zn-0.005 catalysts to be about the half of that over the HMOR catalyst.We attributed it to the change of the acid properties, which further change the rate of coke deposition.
Zhitao ZhangNa ZhaoKui MaQingpeng ChengJing ZhangLirong ZhengYe TianXingang Li
通过一步水热法制备出具有三维网络结构的氢氧化镍-石墨烯复合材料(Ni(OH)2-GS)。这一独特的结构可以提供良好的离子传输通道,同时可以有效地提高氢氧化镍与电解液的接触面积和材料的导电性。结果表明,Ni(OH)2的质量分数为84%时,复合材料具有最佳的电化学性能,在5 m V·s-1的扫速下比电容为1 461 F·g-1,在100 m V·s-1的扫速下比电容为682 F·g-1(容量保持率为47%),并且具有良好的循环稳定性。
