A novel series of Ce^3+-doped Yb3 Al(5-x)GaxO(12)(x = 0, 1,2, 3,4, 5) powders of ytterbium aluminum gallium garnets were synthesized by high temperature solid-state reaction in a carbon reducing atmosphere. The ytterbium aluminum garnets were characterized by X-ray powder diffraction, UV-Vis diffuse reflectance spectra, photoluminescence spectra and decay curves. Moreover, the substitution effect for the Al^3+ sites with Ga^3+ in 0.5 at%Ce:Yb3 Al(5-x)GaxO(12)(x = 0,1, 2, 3, 4, 5) garnets were discussed. With the increase of Ga^3+ ion concentration, the visible absorption peaks within 400-450 nm have blue shift phenomenon,while the absorption peaks in the range of 330-350 nm and the absorption band edge red shifts.Furthermore, the short decay times are very short with less than 10 ns due to the Yb^3+ + Ce^3+→ Yb^2+ + Ce^4+ electron transfer reaction.
Ru LiJie YinFei DuPeng ZhangShangke PanJianguo Pan