Three novel inorganic-organic hybrid materials, [Cu（imi）2（H2O）（MoO4）]n 1, [Cuz（imi）3（MoO4）E]n.nH2O 2 and [Cu3（imi）2（OH）2（MoO4）2]n 3 （imi = imidazole）, were synthesized and characterized by X-ray single-crystal structure determination. 1 crystallizes in orthorhombic, space group Pca21 with a = 13.382（4）, b = 8.527（2）, c = 9.622（3）A, V = 1098.0（5） A^3 Z = 4, C6H10CuMoN4O5, Mr = 377.66, Dc = 2.285 g/cm^3, F（000） = 740,μ（MoKa） = 3.095 mm^-1, the final R = 0.0256 and wR = 0.0722 for 1896 observed reflections with I 〉 2σ（I）. 2 crystallizes in monoclinic, space group P2t/c with a= 11.170（2）, b = 7.8244（15）, c = 22.631（4）A, β = 115.790（7）°, V = 1780.9（6）A^3 Z = 4, C9H14Cu2Mo2N6O9, Mr = 669.24, Dc= 2.496 g/cm^3, F（000）=1295,μ（MoKa） = 3.792 mm^-1, the final R = 0.0225 and wR = 0.0615 for 3838 observed reflections with I 〉 2σ（I）. 3 crystallizes in monoclinic, space group P21/c with a = 5.5599（19）, b = 23.771（8）, c = 7.3044（18）A , β = 129.356（16）°, V = 746.5（4）A^3, Z = 2, C6H10Cu3Mo2N4O10, Mr = 680.71, Dc = 3.029 g/cm^3, F（000） = 650,μ（MoKa） = 5.900 mm^-1, the final R = 0.0215 and wR = 0.0524 for 1620 observed reflections with I 〉 2σ（I）.
The title compound,[Cu4I4（C4H8N4）4],has been synthesized and characterized by single-crystal X-ray diffraction analysis.It crystallizes in monoclinic,space group Pbca,with a=18.1851（10）,b=9.3697（5）,c=19.8034（10）A,V=3374.3（3）A^3,C16H32Cu4I4N16,Mr=1210.34,Z=4,Dc=2.383 g/cm^3,μ=6.183 mm^-1,F（000）=2272,S=1.032,the final R=0.0309 and wR=0.1180 for 3854 observer reflections（I〉2σ（I））.The structure of the title compound consists of tetranuclear copper cluster units bridged by the halogen atoms with the 3,5-dimethyl-4-aminotriazole ligands coordinated to the metal ions through the triazole nitrogen atoms.The luminescent property of 1 was also studied.
＜正＞POMs,as building blocks to construct the solid-state materials with versatile organic ligands or charge com...
Yi-Ming Xie Can-Zhong Lu~* The State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences,Fuzhou 350002,China.
＜正＞Coordination polymers with different networks,which have potential functions, including nonlinear optics,ca...
Zhen-Lan Fang Qi-Sheng Zhang Xiao-Yuan Wu Shan-Ci Chen Can-Zhong Lu~* The State Key Laboratory of Structure Chemistry,Fujian Institute of Research on the Structure of Matter,The Chinese Academy of Science,Fuzhou,Fujian,350002,Pepole''s Republic of China
The title compound, [Cu2（DMPz）2PMo12O40]·HDMPz （1, DMPz = 2,5-dimethyl pyrazine）, has been synthesized and characterized by single-crystal X-ray diffraction analysis. It crystallizes in triclinic, space group P1 with a = 11.075（2）, b = 11.551（2）, c = 11.886（2） A.α = 106.352（2）, β = 109.862（3）, γ = 109.504（1）°, V = 1206.8（3） A3, C18H26CU2Mo12N6O40P, Mr = 2275.78, Z = 1, Dc = 3.131 g/cm3, μ = 4.011 mm^-1, F（000） = 1073, S = 1.066, the final R = 0.0389 and wR = 0.1056 for 3739 observed reflections with I 〉 2σ（I）. The structural analysis indicates that the title compound is composed of Keggin clusters [PMo12O40]3- connected by one-dimensional [CB（DMPz）]2n^2n＋ chains to form a two-dimensional grid layer with holes occupied by monoprotonated DMPz molecules. In the solid of the title compound, the 2D grid layers are stacked together in an ABAB packing mode.
A three-dimensional supramolecular architecture, {[Co（proH）（H2O）3]2[P2Mo5O23]}·7H2O （1, pro = praline）, has been synthesized and characterized by IR, elemental analysis, thermogravimetric analysis, and single-crystal X-ray diffraction. 1 crystallizes in monoclinic, space group C2 with a = 20.600（3）, b = 11.6980（11）, c = 9.2944（10）A, β = 107.837（4）°, V = 2132.1（4） A^3, Z = 2, C10H46Co2Mo5N2O40P2, Mr = 1493.99, Dc = 2.327 g/cm^3, F（000） = 1468, μ（MoKα） = 2.375 mm^-1, the final R = 0.0339 and wR = 0.0844 for 4169 observed reflections with I 〉 2σ（I）. Singlecrystal X-ray crystallographic analysis reveals that the helical water chains and {[Co（proH）- （H2O）3]2[P2Mo5O23]}n chains are perpendicular to each other and extend into an overall three-dimensional supramolecular architecture by hydrogen-bonding interactions. The magnetic investigation indicates weak antiferromagnetic interactions in the compound.
＜正＞Exploitation of polyoxometalates（POMs）as building blocks to construct organic-inorganic hybrid materials ha...
Xiao-Yuan Wu Can-Zhong Lu~* The State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences,Fuzhou 350002,China.
＜正＞The design and synthesis lanthanide-transition metal of heterometallic complexes, such as 3d-4f or 4d-4f me...
Fei Wang Xiao-Yuan Wu Quan-Guo Zhai Zhen-Guo Zhao Xiao-Yu Jiang Yi-Ming Xie Can-Zhong Lu~* State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences,Fuzhou,Fujian 350002,P.R.China.
＜正＞Polynuclear nickel（Ⅱ）co-orination compounds with derivatives of 1,2,4-triazole have been of growing researc...
Zhen-Guo Zhao Xiao-Yuan Wu Can-Zhong Lu~* State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences,Fuzhou,Fujian 350002,P.R.China.
