One dimensional inorganic/organic heterojunction nanomaterials have gained extensive attention in materials science because of their outstanding optical and electrical properties. Strong interactions between the inorganic and organic units can lead to novel or improved physical or chemical performance relative to that of the individual components, realizing synergistic ("1+1>2") performance. It is of great scientific significance for the development of basic scientific research: Understanding and interpretation the law of molecular self-assemble, controlling the self-assemble of low dimensional molecular aggregation with high ordered degree in large area through tailoring the molecular structure and the interaction forces, understanding the synergy drive mechanism produced by the weak interactions between the molecular aggregations then optimizing the original function through the hybrid/ heterojunction self-assemble. In this paper, we discuss the synthetic methods for preparing heterojunctions incorporating diverse components and their potential applications in the fields of electronics and optics.
Porphyrins are abundant in nature. They have been frequently employed as building blocks in the construction of nanoarchitectures and functional supramolecular systems. Recently, a series of novel porphyrin molecules including small molecules and polymers have been originally designed and synthesized with the aim of producing nanostructures with controllable-growth and materials with high-performance. Literature coverage is through 2004–2012. This review gives a full summary of related studies in our group.
A facile procedure for the synthesis of dithieno[5,6-b:11,12-b0]coronene-2,3,8,9-tetracarboxylic tetra(2-ethylhexyl)ester(DTCTTE-EH) from readily available perylene-3,4,9,10-tetracaroboxylic dianhydride is described. The electronic properties of DTCTTE-EH were elucidated on the basis of UV–vis spectra, emission spectrum and electrochemical measurement, which demonstrate that DTCTTE is a new class of components for promising semiconducting materials.
Chun ZhanYou-Yu JiangMing-Yan YangLu-Hua LuSheng-Qiang Xiao
