＜正＞Fused/bridged/spiro carbocyclic ring scaffolds are one of most important motifs in natural and synthetic or...
Jia Liu,~(1,2) Xi Wang,~1 Chang-Liang Sun,~1 Bi-Jie Li,~1 Min Wang,~2 Zhang-Jie Shi~(*1,3) 1 Beijing National Laboratory of Molecular Sciences(BNLMS) and Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education,College of Chemistry and Molecular Engineering and Green Chemistry Center,Peking University,Beijing 100871 and Department of Chemistry,2 University of Agriculture of China,Beijing 100094 and 3 State Key laboratory of Organometallic Chemistry,Shanghai Institute of Organic Chemistry,Chinese Academy of Sciences,Shanghai 200032,China
＜正＞Palladium-catalyzed highly regioselective carbonylation of substituted N,N-dimethylbenzylamines was develop...
Hu Li,~1 Gui-Xin Cai,~1 Zhang-Jie Shi~(*1,2) 1 Beijing National Laboratory of Molecular Sciences(BNLMS),PKU Green Chemistry Center and Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education,College of Chemistry, Peking University,Beijing 100871,China 2 State Key Laboratory of Organometallic Chemistry,Chinese Academy of Sciences,Shanghai 200032,China
＜正＞The transition metal catalyzed reactions of diazo compounds have been well-established as powerful approach...
Lei Zhou,Fei Ye,Yan Zhang and Jianbo Wang~* Beijing National Laboratory for Molecular Sciences(BNLMS),Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education,College of Chemistry,Peking University,Beijing 100871,China
＜正＞Previously,we have reported the nickel-catalyzed cross-coupling of aryl carboxylates with aryl boron and ar...
Bi-Jie Li,Li Xu,and Zhang-Jie Shi~* Beijing National Laboratory of Molecular Sciences(BNLMS) and Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education,College of Chemistry and Green Chemistry Center,Peking University,Beijing 100080,China
A facile synthesis of various allyl sulfonamides based on imidation of allyl sulfides with chloramine-T and sub- sequent [2,3]-sigmatropic rearrangement has been achieved without metal catalysts. The reaction completes smoothly within 10 min, providing excellent yields in environment friendly solvent of alcohol. Functional groups such as bromine, hydroxyl, protected amido and aldehyde are tolerant under this condition.
