The feasibility of utilization of flue gas desulfurization (FGD) gypsum and Class-C fly ash (CFA) to prepare CFA-based geopolymer were studied. The results showed that geopolymer made from 90% CFA and 10% FGD gypsum (FGDG) which was thermally treated at 800 ℃ for 1 h obtained the better compressive strength of 37.0 MPa. The micro characteristics and structures of the geopolymer samples of CFA and CFA-FGDG were tested by XRD, FT-IR, and SEM-EDXA after these samples cured at 75 ℃ for 8 h followed by 23 ℃ for 28 d. Both the geopolymer samples of CFA and CFA-FGDG have significant asymmetric stretching of Al-O/Si-O bonds and Si-O-Si / Si-O-Al bending band. In geopolymer sample of CFA-FGDG, a small quantity of lathy products probably being the ettringite wrapped over the spherical fly ash particle, and the concentration of sulfur is much more than that in geopolymer sample of CFA. It is indicated that FGD gypsum may react during alkali-activated and geopolymeric process.
The feasibility of high calcium fly ash(CFA)-based geopolymers to fix heavy metals were studied.The CFA-based geopolymers were prepared from CFA,flue gas desulfurization gypsum(FGDG),and water treatment residual(WTR).The static leaching showed that heavy metals concentrations from CFAbased geopolymers were lower than their maximum concentration limits according to the U.S.environmental protection law.And the encapsulated and fixed ratios of heavy metals by the CFA-based geopolymers were 96.02%-99.88%.The dynamic real-time leaching experiment showed that concentration of Pb(II) was less than 1.1 μg / L,Cr(VI) less than 3.25 mg / L,while Hg(II) less than 4.0 μg / L.Additionally,dynamic accumulated leaching concentrations were increased at the beginning of leaching process then kept stable.During the dynamic leaching process,heavy metals migrated and accumulated in an area near to the solid-solution interface.When small part of heavy metals in 'the accumulated area' breached through the threshold value of physical encapsulation and chemical fixation they migrated into solution.The dynamic leaching ratios and effective diffusion coefficients of heavy metals from CFA-based geopolymer were very low and the long-term security of heavy metals in CFA-based geopolymer was safe.
The workability and durability of a type of sustainable concrete made with steel slag powder were investigated. The hydrated products of cement paste with ground granulated blast furnace slag(GGBFS) alone or with a combined admixture of GGBFS-steel slag powder were investigated by X-ray diffraction(XRD). Furthermore, the mechanism of chemically activated steel slag powder was also studied. The experimental results showed that when steel slag powder was added to concrete, the slumps through the same time were lower. The initial and fi nal setting times were slightly retarded. The dry shrinkages were lower, and the abrasion resistance was better. The chemically activated steel slag powder could improve compressive strengths, resistance to chloride permeation and water permeation, as well as carbonization resistance. XRD patterns indicated that the activators enhanced the formation of calcium silicate hydrate(C-S-H) gel and ettringite(AFt). This research contributes to sustainable disposal of wastes and has the potential to provide several important environmental benefi ts.
Hydration heat behavior and kinetics of blended cement containing up to 20% MSWI fly ash were investigated based on its hydration heat evolution rate measured by isothermal calorimeter. Kinetics parameters, N and K, and hydration degree, Ca(OH)2 content, were also calculated and analyzed. According to the experimental results, the induction period was elongated, the second heat evolution peak was in advance, and the third hydration heat peak could be detected due to MSWI fly ash pozzolanic reaction. The hydration reaction rate was controlled by nucleation kinetics in the acceleration period and then by diffusion in the decay period, but in the deceleration period, the hydration experienced a dual controlling reaction of autocatalytic chemical reaction and diffusion. The hydration rate of blended cement was faster. Ca(OH)2 content increased before 14 days.
The feasibility of flue gas desulphurization(FGD) as concrete admixture was studied. A combined concrete admixture of the thermally-treated FGD gypsum and slag powder was explored. The FGD gypsum was roasted at 200 ℃ for 60 min and then mixed with the slag powder to form FGD gypsum-slag powder combined admixture in which the SO 3 content was 3.5wt%. Cement was partially and equivalently replaced by slag powder alone or FGD gypsum-slag powder, at concentration of 25wt%, 40wt%, and 50wt%, respectively. The setting times, hydration products, total porosity and pore size distributions of the paste were determined. The compressive strength and drying shrinkage of cement mortar and concrete were also tested. The experimental results show that, in the presence of FGD gypsum, the setting times are much slower than those of pastes in the absence of FGD gypsum. The combination of FGD gypsum and slag powder provides synergistic benefits above that of slag powder alone. The addition of FGD gypsum provides benefit by promoting ettringite formation and forms a compact microstructure, increasing the compressive strength and reduces the drying shrinkage of cement mortar and concrete.
