The feasibility of flue gas desulphurization(FGD) as concrete admixture was studied. A combined concrete admixture of the thermally-treated FGD gypsum and slag powder was explored. The FGD gypsum was roasted at 200 ℃ for 60 min and then mixed with the slag powder to form FGD gypsum-slag powder combined admixture in which the SO 3 content was 3.5wt%. Cement was partially and equivalently replaced by slag powder alone or FGD gypsum-slag powder, at concentration of 25wt%, 40wt%, and 50wt%, respectively. The setting times, hydration products, total porosity and pore size distributions of the paste were determined. The compressive strength and drying shrinkage of cement mortar and concrete were also tested. The experimental results show that, in the presence of FGD gypsum, the setting times are much slower than those of pastes in the absence of FGD gypsum. The combination of FGD gypsum and slag powder provides synergistic benefits above that of slag powder alone. The addition of FGD gypsum provides benefit by promoting ettringite formation and forms a compact microstructure, increasing the compressive strength and reduces the drying shrinkage of cement mortar and concrete.
The feasibility of high calcium fly ash(CFA)-based geopolymers to fix heavy metals were studied.The CFA-based geopolymers were prepared from CFA,flue gas desulfurization gypsum(FGDG),and water treatment residual(WTR).The static leaching showed that heavy metals concentrations from CFAbased geopolymers were lower than their maximum concentration limits according to the U.S.environmental protection law.And the encapsulated and fixed ratios of heavy metals by the CFA-based geopolymers were 96.02%-99.88%.The dynamic real-time leaching experiment showed that concentration of Pb(II) was less than 1.1 μg / L,Cr(VI) less than 3.25 mg / L,while Hg(II) less than 4.0 μg / L.Additionally,dynamic accumulated leaching concentrations were increased at the beginning of leaching process then kept stable.During the dynamic leaching process,heavy metals migrated and accumulated in an area near to the solid-solution interface.When small part of heavy metals in 'the accumulated area' breached through the threshold value of physical encapsulation and chemical fixation they migrated into solution.The dynamic leaching ratios and effective diffusion coefficients of heavy metals from CFA-based geopolymer were very low and the long-term security of heavy metals in CFA-based geopolymer was safe.
