CoC 的导致激光的荧光刺激光谱被记录在光谱到 CoC 分子被劈啪作响的钴原子的反应在超声的喷气下面与甲醇在生产的 22000 厘米 −1, 的从 13500 厘米 −1 的区域使条件凉下来。许多可见光谱被分到在 X 2Σ+ 地面状态和 F 2Σ+ 状态之间的转变。是分配的 11 个乐队(v'= 3 13, 0 ) F 2Σ+-X2Σ+ 乐队系统的转变被观察,旋转联盟者分析了。为 F 2Σ+ 状态的平衡常数是 T e = 13628 厘米 −1,ω
e = 669 厘米 −1,ω
e χ e = 4.3 厘米 −1, B e = 0.546 厘米 −1, 和 R e = 1.758 Å
。一些新乐队被观察。
Jing-ru Guo Zhao-xia Zhang Ting-ting Wang Cong-xiang Chen Yang Chen
Kr atoms were produced in their metastable states 4p55s [3/2]2 and 4p55s' [1/2]0 in a pulsed DC dis-charge in a beam,and subsequently excited to the even-parity autoionizing Rydberg states 4p5np' [3/2]1,2,[1/2]1 and 4p5nf' [5/2]3 using single photon excitation.The excitation spectra of the even-parity autoionizing resonance series from the metastable Kr were obtained by recording the autoionized Kr+ ions with time-of-flight ion detection in the photon energy range of 29000-40000 cm1.A wealth of autoionizing resonances were newly observed,from which more precise and more systematic spec-troscopic data of the level energy and quantum defects were derived.
LI ChunYanWANG TingTingZHEN JunFengZHANG QunCHEN Yang