We conducted measurements of black carbon （BC） aerosol in Jiaxing, China during autumn from September 26 to November 30, 2013. We investigated temporal and diurnal variations of BC, and its cor relations with meteorological parameters and other major pollutants. Results showed that hourly mass concentrations of BC ranged from 0.2 to 22.0 μg/m3, with an average of 5.1 μg/ms. The diurnal variation of BC exhibited a bimodal distribution, with peaks at 07：00 and 18：00. The morning peak was larger than the evening peak. The mass percentages of BC in PM2.s and PM10 were 7.1%and 4.8g, respectively. The absorption coefficient of BC was calculated to be 44.4 Mm-1, which accounted for 11.1% of the total aerosol extinction. BC was mainly emitted from local sources in southwestern Jiaxing where BC concentrations were generally greater than 11μg/m3 during the measurement period. Correlation analysis indicated that the main sources of BC were motor vehicle exhaust, and domestic and industrial combustion.
Lijuan ShenLi LiSheng LuXiaohan ZhangJie LiuJunlin AnGuojun ZhangBo WuFei Wang
Chemical composition, hourly counts, and sizes of atmospheric carbonaceous particles were measured to investigate their mixing state on clear and hazy days. 823,122 carbonaceous particles with sizes 0.2-2.0μm was analyzed using a single-particle aerosol mass spectrometer from 1st to 17th January 2013. Particle types included biomass/biofuel burning particles （biomass）, element carbon （EC-dominant） particles that were also mixed with biomass/biofuel burning species （EC-biomass） or secondary species （EC-secondary）, organic carbon （OC）, internally mixed OC and EC （OCEC）, ammonium-containing （ammo- nium） and sodium-containing （sodium） particles. On clear days the top ranked carbonaceous particle types were biomass （48.2%）, EC-biomass （15.7%）, OCEC （11.1%）, and sodium （9.6%）, while on hazy days they were biomass （37.3%）, EC-biomass （17,6%）, EC-secondary （16.6%）, and sodium （12.7%）. The fractions of EC-secondary, ammonium （10%）, and sodium particle types were elevated on hazy days. Numbers of EC-secondary particles were more than four times those on clear days （4.1%）. Thus, carbonaceous particles mixed with ammonium, nitrate and sulfate during aging and transport, enhancing their light extinction effects and hygroscopic growth under high relative humidity on hazy days, further reducing visibility. Our real-time single-particle data showed that changes to mixing state had a significant impact on light extinction during haze events in Nanjing.
