在TMEDA(四甲基乙基二胺)-Na_2O-SiO_2-Al_2O_3-H_2O体系(Ⅰ),Na_2O-K_2O-Al_2O_3-SiO_2-H_2-HCO_3^-CO_3^(2-) (Ⅱ)及Py(吡啶)-PrNH_2(正丙胺)-HF-SiO_2-H_2O体系(Ⅲ)中,分别合成了纯相FER沸石及FER硅沸石.用粉末XRD,FT-IR,^(29)Si MAS NMR及TG/DTA等表征其结构性质,并用超微量电子真空吸附天平测定这些沸石样品对正己烷,甲醇和水的吸附等温线.结果表明:各体系合成的样品虽然结晶度高,呈现出FER沸石的典型结构特征,但由于它们的组成和晶格微结构不同,热稳定性与吸附性质有明显的差异.在(Ⅰ)体系中合成的FER沸石层错缺陷少,晶格完美,正己烷与甲醇的吸附量可达到理论值,结构破坏温度为1190℃.红外精细谱及^(29)Si MAS NMR高分辨谱证明FER硅沸石具有十分完美的骨架结构.由于晶胞收缩,它对正己烷与甲醇吸附量略低于理论值,并呈现出高度的疏水性.它的结构破坏温度高于1300℃.在(Ⅱ)体系中合成的FER型沸石结构缺陷多,沸石孔中的钾离子不易被质子完全交换.它的正己烷与甲醇吸附量均较低,而水的吸附量相对较高.吸附现象表明,正己烷和甲醇都被吸附于FER沸石的十元环主孔道中,分压较高时,甲醇可通过八元环进入小笼,而水的吸附性质则主要与各样品的Si-OH缺陷及骨架中的阳离子含量有关.
The interaction between the adsorbed methylamine(MA) and siliceous FAU zeolite with a perfect framework is investigated with XRD, 29 Si and 13 C MAS NMR and FTIR. As methylamine is loaded into the zeolite, the crystal structure of the zeolite changes. One peak splits to four peaks for the 29 Si MAS NMR spectrum, and the IR vibration of framework with a high resolution become simpler. The fact indicates that there is a strong interaction between adsorbed methylamine and Si—O framework of FAU zeolite, leading to high A T value of affinity index for methylamine on the zeolite. The order structure of MA/FAU associate is discussed as well.
用粉末XRD,FT—IR,^(29)Si MAS NMR,对高硅HZSM—5沸石及疏水硅沸石Silicalite-Ⅰ进行结构性质表征.在室温下,疏水硅沸石具有ZSM—5的单斜对称性.它的红外骨架振动谱及高分辨^(29)Si固体核磁共振谱均显示出高的分辨率.在红外光谱中,3700和3500^(-1)左右的表面Si-OH基振动消失.表明疏水硅沸石晶格中的[SiO_4]四面体排列完美.由—Si—O—Si—构成的微孔表面,具有优良的疏水性.
