为了研究氧气-空气混合助燃超音速火焰喷涂过程中预混气体当量比对焰流特性的影响，基于FLUENT软件建立了焰流的计算流体力学（CFD）模型．运用有限元软件LS-DYNA来研究不同粒径Ni60粒子的撞击行为，并与粒子截面的 SEM 形貌进行了对比．结果表明：合理的丙烷和全部氧气的当量比应小于1.2；在燃气过量时，焰流中过多的N2会引起熄燃；与基体结合较好的粒子尺寸为20～40,μm；粒径小于20,μm的粒子速度高，回弹力大，与基体结合力差；粒径大于50,μm的粒子速度低，熔化不充分，粒子与基体结合面缺陷较多．
This work was attempted to modify the current technology for thermal barrier coatings（TBCs） by adding an additional step of surface modification,namely,supersonic fine particles bombarding（SFPB） process,on bond coat before applying the topcoat.After isothermal oxidation at 1000 °C for different time,the surface state of the bond coat and its phase transformation were investigated using X-ray diffraction（XRD）,scanning electron microscopy（SEM） equipped with energy-dispersive X-ray spectrometry（EDS）,transmission electron microscopy（TEM） and Cr3＋ luminescence spectroscopy.The dislocation density significantly increases after SFPB process,which can generate a large number of diffusion channels in the area of the surface of the bond coat.At the initial stage of isothermal oxidation,the diffusion velocity of Al in the bond coat significantly increases,leading to the formation of a layer of stable α-Al2O3 phase.A great number of Cr3＋ positive ions can diffuse via diffusion channels during the transient state of isothermal oxidation,which can lead to the presence of（Al0.9Cr0.1）2O3 phase and accelerate the γ→θ→α phase transformation.Cr3＋ luminescence spectroscopy measurement shows that the residual stress increases at the initial stage of isothermal oxidation and then decreases.The residual stress after isothermal oxidation for 310 h reduces to 0.63 GPa compared with 0.93 GPa after isothermal oxidation for 26 h.In order to prolong the lifespan of TBCs,a layer of continuous,dense and pure α-Al2O3 with high oxidation resistance at the interface between topcoat and bond coat can be obtained due to additional SFPB process.
